Cu(II)-mediated oxidative intermolecular ortho C-H functionalisation using tetrahydropyrimidine as the directing group

Tetrahydropyrimidine works efficiently as a directing group in Cu(II)-mediated oxidative aromatic C-H functionalisation for the selective introduction of oxygen or nitrogen to the ortho-position.

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 23; pp. 3413 - 3415
Main Authors Mizuhara, Tsukasa, Inuki, Shinsuke, Oishi, Shinya, Fujii, Nobutaka, Ohno, Hiroaki
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2009
Subjects
Aniline Compounds - chemistry
Carbon - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
Copper - chemistry
Hydrogen - chemistry
Hydroxylation
Oxidation-Reduction
Physical Sciences
Pyrimidines - chemistry
Science & Technology
DIRECT ORTHO-ARYLATION
ACTIVATION
ONE-POT SYNTHESIS
ACIDS
RUTHENIUM-CATALYZED ADDITION
COUPLING REACTION
AROMATIC IMINES
TANDEM CYCLIZATION
ARYL
CARBON-HYDROGEN BONDS
Online AccessGet full text

Cover

More Information
Summary:Tetrahydropyrimidine works efficiently as a directing group in Cu(II)-mediated oxidative aromatic C-H functionalisation for the selective introduction of oxygen or nitrogen to the ortho-position.
ISSN:1359-7345
1364-548X
DOI:10.1039/b905586j