Cyclosiloxane polymer bearing dynamic boronic acid: synthesis and bottom-up nanocoating
The paper describes facile synthesis of boronic ester-containing polycyclosiloxane (pCS-ABPE) through a one-pot-two-step hydrosilylation reaction that allows control of the functionalization efficiency stoichiometrically from zero to 100%. The combination of cyclosiloxane and boronic acid groups is...
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Published in | Polymer chemistry Vol. 1; no. 38; pp. 5228 - 5235 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Cambridge
Royal Society of Chemistry
14.10.2019
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Subjects | |
Online Access | Get full text |
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Summary: | The paper describes facile synthesis of boronic ester-containing polycyclosiloxane (pCS-ABPE) through a one-pot-two-step hydrosilylation reaction that allows control of the functionalization efficiency stoichiometrically from zero to 100%. The combination of cyclosiloxane and boronic acid groups is expected to benefit from excellent thermal properties, flexible polymer backbone, and chemical resistance of the polycyclosiloxane part and the dynamic chemical properties of the boronic acid part to generate novel and functional hybrid polymers. Results showed that the hydrolysis of pCS-ABPE gave rise to a boronic-acid-containing polycylcosiloxane (pCS-AB) with good self-assembly nanofilm formation (6 nm film thickness) on plastic substrates through dip-coating method, mainly because of its low surface free energy (∼20 mN m
−1
). In addition, the dynaminc characteristics of boronic acid groups in the pCS-AB film were demonstrated through water soluble dye Alizarin Red S (ARS) coating. The film surface underwent reversible coating through the boronic acid equilibrium: formation of the dynamic covalent bonding (pCS-AB-ARS) and bond deformation with Zn ions for ARS-Zn complex formation. The performance makes the self-assembly nanofilm promising for chemical sensor applications.
Boronic acid-containing polycyclosiloxane showed unique self-assembly nanofilm formation (6 nm film thickness) on various substrates and provided film-based metal ion sensor capability through dynamic covalent bonding. |
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Bibliography: | 10.1039/c9py00855a Electronic supplementary information (ESI) available. See DOI |
ISSN: | 1759-9954 1759-9962 |
DOI: | 10.1039/c9py00855a |