Transition metal-complexed catenanes and rotaxanes as molecular machine prototypes

Transition metal-containing catenanes and rotaxanes are ideally suited to build molecular machines and motors; in the present review article, three examples from our group are discussed which consist of (i) a fast-moving electrochemically-driven pirouetting machine, (ii) a linear rotaxane dimer whos...

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 12; p. 1507
Main Author Sauvage, Jean-Pierre
Format Journal Article
LanguageEnglish
Published England 28.03.2005
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Summary:Transition metal-containing catenanes and rotaxanes are ideally suited to build molecular machines and motors; in the present review article, three examples from our group are discussed which consist of (i) a fast-moving electrochemically-driven pirouetting machine, (ii) a linear rotaxane dimer whose behaviour is reminiscent of muscles, in the sense that it can be stretched or contracted and (iii) a light-driven machine consisting of a catenane constructed around a ruthenium(II) centre.
ISSN:1359-7345
DOI:10.1039/b500680p