An efficient copper-catalyzed oxidative Mannich reaction between tertiary amines and methyl ketones

An efficient oxidative Mannich reaction between tertiary amines and unmodified methyl ketones has been developed, using copper salts as the catalyst and O-2 as the oxidant.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 8; pp. 953 - 955
Main Authors Shen, Youming, Li, Mo, Wang, Sizhuo, Zhan, Tianguang, Tan, Ze, Guo, Can-Cheng
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2009
Subjects
Amines - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
Copper - chemistry
Mannich Bases - chemistry
Molecular Structure
Oxidation-Reduction
Physical Sciences
Science & Technology
CINCHONA ALKALOIDS
SP C-H
ASYMMETRIC-SYNTHESIS
DEHYDROGENATIVE-COUPLING CDC
NITROGEN ATOM
SODIUM-CYANIDE
BONDS ADJACENT
ANTI-MANNICH
BETA-AMINO
DERIVATIVES
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Summary:An efficient oxidative Mannich reaction between tertiary amines and unmodified methyl ketones has been developed, using copper salts as the catalyst and O-2 as the oxidant.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b819657e