Physico-chemical properties of silica aerogels prepared from TMOS/MTMS mixtures

• Published in: Journal of porous materials Vol. 18; no. 5; pp. 567 - 572
• Main Authors: Ingale, S. V., Wagh, P. B., Tripathi, A. K., Kamble, V. S., Kumar, Ratanesh, Gupta, Satish C.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.10.2011; Springer Nature B.V
• Subjects: Aerogels; Catalysis; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Density; Moisture content; Physical Chemistry; Precursors; Silica aerogels; Solvent extraction; Surface area; Silica aerogels; Acid–base catalysis; Thermal analysis; FTIR; Hydrophobic
• ISSN: 1380-2224; 1573-4854
• DOI: 10.1007/s10934-010-9410-4

In the present work, results on the physico-chemical properties of the silica aerogels prepared by sol–gel process using mixtures of TMOS and MTMS as precursor are reported. The wide range of precursor mixture was studied with ratio of MTMS/TMOS in precursor mixtures as 0:100, 25:75, 50:50, 75:25, and 100:0 by volume. The gels with these precursor mixtures were successfully prepared using two step acid–base catalysis for gelation. Acetic acid (0.001 M) and NH 4 OH (1.5 M) were used for catalysis and resulting alcogels were subsequently dried by supercritical solvent extraction method. FTIR spectroscopy revealed that the aerogels show more intense peak at 1,260 and 790 cm −1 attributed to Si–CH 3 resulting in more hydrophobic nature and these results were concurrent with adsorbed water content measurements made using Karl Fischer’s titration technique. The resulted aerogels were characterized using differential thermal analysis, thermo gravimetric analysis and surface area measurements. The surface area measurements showed an interesting trend that the surface area increased from 395 to 1,037 m 2 /g with increase in MTMS content in the precursor mixture from 0 to 50% and then again decreased to 512 m 2 /g for further increase in MTMS content from 50 to 100% in the precursor mixture. It was observed from our studies that silica aerogels prepared using a starting mixture of 50% TMOS and 50% MTMS resulted in high moisture resistance (adsorbed water content of 0.721% w/w), low density of 90 kg/m 3 and the highest surface area of 1,037 m 2 /g, which has great potential for catalysis support applications.