Recent advances in the Suzuki-Miyaura cross-coupling reaction using efficient catalysts in eco-friendly media

The ever-increasing interest in the Suzuki-Miyaura cross-coupling reaction (SMR) and its applications, with more than 40 years of history, has increased exponentially in the last decade, which speaks volumes about its efficiency and effectiveness. This widely used powerful method provides a practica...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 21; no. 3; pp. 381 - 45
Main Authors Hooshmand, Seyyed Emad, Heidari, Bahareh, Sedghi, Roya, Varma, Rajender S
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2019
Subjects
Carbon
Catalysis
Catalysts
Chemical reactions
Chemical synthesis
Cobalt
Cross coupling
Fine chemicals
Gold
Green chemistry
Industrial applications
Literature reviews
Nickel
Organic chemistry
Palladium
Polymers
Silver
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Summary:The ever-increasing interest in the Suzuki-Miyaura cross-coupling reaction (SMR) and its applications, with more than 40 years of history, has increased exponentially in the last decade, which speaks volumes about its efficiency and effectiveness. This widely used powerful method provides a practical synthetic route for the direct formation of carbon-carbon bonds, which has found considerable academic and industrial use for the production of polymers, fine chemicals and materials, in addition to total synthesis and pharmaceuticals. Green chemistry predicates the use of environmentally-benign media in organic transformations and in recent years, catalytic systems have been introduced in diverse and neoteric green media for SMR. In view of the widespread popularity, there is the need for a comprehensive understanding of the various greener strategies introduced for this important reaction encompassing diverse catalytic systems based on palladium, nickel, gold, ferrites, copper, silver, and cobalt. The present review embodies literature from 2008 onward that covers the SMR using efficient catalysts in various green media. The ever-increasing interest in the Suzuki-Miyaura cross-coupling reaction (SMR) and its applications, with more than 40 years of history, has increased exponentially in the last decade, which speaks volumes about its efficiency and effectiveness; recent improvements in terms of efficient catalysts in benign media are highlighted.
Bibliography:Seyyed Emad Hooshmand was born in Iran, in 1988 and received his B.Sc. in Chemistry from Bu-Ali Sina University, Hamedan, in 2011, and his M.Sc. in Organic Chemistry from Kharazmi University, in 2013. He started his Ph.D. studies at Shahid Beheshti University, Tehran, in 2014, and was awarded the Shahid Shahriari research fellowship in 2017. His current research interests are focused on green chemistry, metal-catalyzed cross-coupling reactions and multi-component reactions based on dithiocarbamates and isocyanides. He is the author of over 25 scientific articles, including, reviews, and a book chapter.
Bahareh Heidari was born in Qorveh/Kurdistan, Iran, in 1989. She received her B.Sc. in Chemistry from Razi University, Kermanshah in 2011, and her M.Sc. in Organic Chemistry from Shahid Beheshti University, Tehran under the supervision of Dr Mohammad Reza Nabid, in 2013. She is currently working towards her Ph.D. in Organic Chemistry under the supervision of Prof. Majid M. Heravi with Dr Roya Sedghi as an advisor. Her research interest involve the synthesis of polymeric nanocomposites as catalyst, colorimetric sensors and molecularly imprinted polymers.
Roya Sedghi was born in 1980 in Tehran and received her B.Sc. degree from the Tehran Azad University of Iran in 2002 before being accepted for M.Sc. at Shahid Beheshti University. She completed her Ph.D. under the supervision of Professor H. Abdi Oskoiee and is presently working at Shahid Beheshti University as an assistant professor. She has authored 50 publications and her research is mainly focused on the application of nanocomposites in various chemistry disciplines such as catalysis and drug delivery. In 2017, she is awarded research project in green chemistry for Life supported by UNESCO, PhosAgro and IUPAC.
Prof. Rajender Varma (H-index 102; 'Highly Cited Researchers' 2016, 2018; Publons awardee 2018) did his PhD from Delhi University, 1976. After postdoctoral research at Robert Robinson Laboratories, Liverpool, England, he was a faculty at Baylor College of Medicine and Sam Houston State University prior to joining the US Environmental Protection Agency in 1999 with appointment at the Regional Centre of Advanced Technologies and Materials, Palacky University at Olomouc, Czech Republic from 2014. He has over 45 years of research experience in the management of multi-disciplinary technical programs. Lately, he is engaged in greener assembly of nanomaterials and the sustainable applications of magnetically retrievable nanocatalysts. He is board member of several international journals, published over 480 papers, and has been awarded 16 US Patents with 35 000 citations.
ISSN:1463-9262
1463-9270
DOI:10.1039/c8gc02860e