Influence of the substituent on selective photocatalytic oxidation of aromatic compounds in aqueous TiO2 suspensions

Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obt...

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Published inChemical communications (Cambridge, England) no. 9; p. 1012
Main Authors Palmisano, Giovanni, Addamo, Maurizio, Augugliaro, Vincenzo, Caronna, Tullio, García-López, Elisa, Loddo, Vittorio, Palmisano, Leonardo
Format Journal Article
LanguageEnglish
Published England 01.01.2006
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Summary:Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obtained.
ISSN:1359-7345
DOI:10.1039/b515853b