Selective site controlled nucleophilic attacks in 5-membered ring phosphate esters: unusual C-O vs. common P-O bond cleavage

Clean endocyclic C-O bond cleavage has been achieved in the reactions of 5-membered phosphate triesters with various nucleophiles.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 47; pp. 5879 - 5881
Main Authors Ashkenazi, N, Zade, SS, Segall, Y, Karton, Y, Bendikov, M
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.12.2005
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
EXOCYCLIC CLEAVAGE
PHOSPHORUS
TRIMETHYL PHOSPHATE
ALKALINE-HYDROLYSIS
PSEUDOROTATION
AB-INITIO
GAS-PHASE
REACTIVITY
MECHANISMS
METHYL ETHYLENE PHOSPHATE
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Summary:Clean endocyclic C-O bond cleavage has been achieved in the reactions of 5-membered phosphate triesters with various nucleophiles.
ISSN:1359-7345
1364-548X
DOI:10.1039/b512117e