The stereochemical course of bromoetherification of enynes

Enynes undergo stereoselective syn intramolecular bromoetherification; the stereochemical course of the reaction was elucidated by X-ray crystallographic studies and by stereospecific synthesis of authentic bromoallenes.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 12; pp. 1419 - 1421
Main Authors Braddock, D. Christopher, Bhuva, Roshni, Perez-Fuertes, Yolanda, Pouwer, Rebecca, Roberts, Craig A., Ruggiero, Andrea, Stokes, Elaine S. E., White, Andrew J. P.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2008
Subjects
Alkadienes - chemical synthesis
Alkadienes - chemistry
Alkynes - chemistry
Chemistry
Chemistry, Multidisciplinary
Hydrocarbons, Brominated - chemical synthesis
Hydrocarbons, Brominated - chemistry
Molecular Conformation
Physical Sciences
Science & Technology
Stereoisomerism
ALCOHOLS
BROMINATION
GENUS LAURENCIA
CONVERSION
NATURAL-PRODUCTS
CYCLIC ETHERS
ASYMMETRIC TOTAL-SYNTHESIS
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Summary:Enynes undergo stereoselective syn intramolecular bromoetherification; the stereochemical course of the reaction was elucidated by X-ray crystallographic studies and by stereospecific synthesis of authentic bromoallenes.
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content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/b800054a