A general approach to triphenylenes and azatriphenylenes: total synthesis of dehydrotylophorine and tylophorine

A convergent and flexible synthesis of substituted triphenylenes, azatriphenylenes, and the cytotoxic alkaloids dehydrotylophorine and tylophorine has been developed.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 39; pp. 4750 - 4752
Main Authors McIver, Andrew, Young, Douglas D., Deiters, Alexander
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2008
Subjects
Alkaloids - chemical synthesis
Alkaloids - chemistry
Alkaloids - radiation effects
Aza Compounds - chemical synthesis
Aza Compounds - chemistry
Aza Compounds - radiation effects
Chemistry
Chemistry, Multidisciplinary
Chrysenes - chemical synthesis
Chrysenes - chemistry
Chrysenes - radiation effects
Cyclization
Indolizines - chemical synthesis
Indolizines - chemistry
Indolizines - radiation effects
Microwaves
Molecular Structure
Phenanthrenes - chemical synthesis
Phenanthrenes - chemistry
Phenanthrenes - radiation effects
Physical Sciences
Science & Technology
Stereoisomerism
ORGANIC-SYNTHESIS
ROUTE
2+2+2 CYCLOADDITION REACTIONS
N-ACYLDIHYDROPYRIDONES
CATALYZED CYCLOTRIMERIZATION
MICROWAVE
COMPLEXES
CHEMISTRY
PHENANTHROINDOLIZIDINE ALKALOIDS
INTRAMOLECULAR ALKYNE CYCLOTRIMERIZATION
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Summary:A convergent and flexible synthesis of substituted triphenylenes, azatriphenylenes, and the cytotoxic alkaloids dehydrotylophorine and tylophorine has been developed.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/b811068a