A Re-Investigation of the Reactions of Amines and Alcohols with 6,9-Bis-(Acetonitrile)Decaborane

The reaction of 6,9-bis-(acetonitrile)decaborane, I, with amines and alcohols has been studied. The products of the reactions of n-BuNH 2 , (n-Bu) 2 NH, PhNH 2 , n-PrNH 2 , (n-Pr) 2 NH, and CH 3 OH with I, which results in retention of the decaborane cage have been fully characterized, including the...

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Published inSynthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry Vol. 36; no. 10; pp. 777 - 785
Main Authors Froehner, Gretchen, Challis, Kelly, Gagnon, Kasey, Getman, Thomas D., Luck, Rudy L.
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 01.12.2006
Subjects
6,9-bis-(acetonitrile)
amidine
boron hydride
decaborane
imidate
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Summary:The reaction of 6,9-bis-(acetonitrile)decaborane, I, with amines and alcohols has been studied. The products of the reactions of n-BuNH 2 , (n-Bu) 2 NH, PhNH 2 , n-PrNH 2 , (n-Pr) 2 NH, and CH 3 OH with I, which results in retention of the decaborane cage have been fully characterized, including the molecular strucutures of 6,9-bis-(N-di-n-butylacetamidine)decaborane and 6,9-bis-(N-phenylacetamidine)decaborane.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533170601028348