Chemical and spectroscopic studies of a new palladium(II) complex with N -acetyl-L-cysteine

Chemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula [Pd(C 5 H 8 NO 3 S) 2 ] · H 2 O or [Pd(NAC) 2 ] · H 2 O. Solid-state 13 C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis...

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Bibliographic Details
Published inJournal of coordination chemistry Vol. 61; no. 22; pp. 3666 - 3673
Main Authors Corbi, P. P., Cagnin, F., Massabni, A. C.
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 20.11.2008
Subjects
C NMR
Infrared spectroscopy
N-acetyl-L-cysteine
Palladium(II)
Thermal analysis
UV-Vis
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Summary:Chemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula [Pd(C 5 H 8 NO 3 S) 2 ] · H 2 O or [Pd(NAC) 2 ] · H 2 O. Solid-state 13 C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis) and infrared (IR) spectroscopic analyses are consistent with coordination of the ligand to palladium(II) through the nitrogen and sulfur atoms in a square-planar geometry. Thermogravimetric and differential thermal analyses confirmed the composition; final residue was identified as metallic palladium.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970802108809