DABCO-Bromine Complex: A Novel Oxidizing Agent for Oxidative Deprotection of THP and Silyl Ethers and Semicarbazones to Corresponding Carbonyl Compounds

A tetrameric DABCO-bromine complex was synthesized, characterized, and utilized as a novel active bromine complex for the oxidative deprotection of THP and silyl ethers and semicarbazones to carbonyl compounds.

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Bibliographic Details
Published inSynthetic communications Vol. 37; no. 17; pp. 2967 - 2973
Main Authors Tajbakhsh, Mahmood, Heravi, Majid M., Habibzadeh, Setareh
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 01.08.2007
Taylor & Francis
Subjects
Chemistry
Chemistry, Organic
DABCO-bromine complex
deprotection
oxidation
Physical Sciences
Science & Technology
semicarbazones
silyl ethers
Tetrahydropyranyl ethers
REAGENT
tetrahydropyranyl ethers
HEXAMETHYLENETETRAMINE-BROMINE
SILICA-GEL
CONVERSION
silyl ethers
deprotection
oxidation
MICROWAVE IRRADIATION
TRIMETHYLSILYL ETHERS
semicarbazones
ALCOHOLS
DABCO- bromine complex
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Summary:A tetrameric DABCO-bromine complex was synthesized, characterized, and utilized as a novel active bromine complex for the oxidative deprotection of THP and silyl ethers and semicarbazones to carbonyl compounds.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910701473234