Crystal structure, and thermal and magnetic properties of 2,4-dinitrobenzoatoterbium(III) complex

The Tb(III) complex containing 2,4-dinitrobenzoate (2,4-DNB), Tb(2,4-DNB) 3 (H 2 O) 2 ] · C 2 H 5 OH has been synthesized and its crystal structure analyzed by X-ray diffraction methods. The complex crystallizes in the triclinic space group P 1 , as a linear polymeric chain in which terbium ions are...

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Bibliographic Details
Published inJournal of coordination chemistry Vol. 60; no. 24; pp. 2703 - 2712
Main Authors Yun, Sock-Sung, Park, Youn-Bong, Yeon, Jeong-Ho, Kim, Eun-Ju, Kim, Don
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 15.12.2007
Subjects
Crystal structure
Magnetic measurements
Terbium complex
Thermal analysis
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Summary:The Tb(III) complex containing 2,4-dinitrobenzoate (2,4-DNB), Tb(2,4-DNB) 3 (H 2 O) 2 ] · C 2 H 5 OH has been synthesized and its crystal structure analyzed by X-ray diffraction methods. The complex crystallizes in the triclinic space group P 1 , as a linear polymeric chain in which terbium ions are bridged by carboxylate groups. The eight-coordinate Tb ion with six carboxylate groups and two water molecules forms a slightly distorted square antiprism. Thermal and magnetic properties of the terbium complex were also studied.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970701306231