Tunable wettability of monodisperse core-shell nano-SiO2 modified with poly(methylhydrosiloxane) and allyl-poly(ethylene glycol)

• Published in: Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 441; pp. 16 - 24
• Main Authors: Zhang, Yu, Chen, Hongling, Wen, Yanjia, Yuan, Yongbing, Wu, Wei, Liu, Chang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 20.01.2014
• Subjects: Allyl-poly(ethylene glycol); Contact angle; Emulsions; Ethanol; Ethyl alcohol; Glycols; Nanostructure; Poly(methylhydrosiloxane); Surface modification; Thermal analysis; Tunable wettability; Vinyl–SiO2; Wettability; Vinyl–SiO2; Surface modification; Tunable wettability; Allyl-poly(ethylene glycol); Poly(methylhydrosiloxane)
• ISSN: 0927-7757; 1873-4359
• DOI: 10.1016/j.colsurfa.2013.08.079

•Vinyl–SiO2 was synthesized from tetraethyl orthosilicate and vinyltriethoxysilane.•Vinyl–SiO2 was modified with PMHS and APEG via two-step hydrosilylation reactions.•The resultant hybrid nanoparticles possessed tunable wettability.•The modified SiO2 showed uniform monodispersity both in ethanol and toluene.•The modified SiO2 with moderate wettability could emulsify silicone oil/water system. In this paper, vinyl-capped silica nanoparticles (V–SiO2) were first synthesized from tetraethyl orthosilicate (TEOS) and vinyltriethoxysilane (VTEOS). Then the V–SiO2 nanoparticles were modified with poly(methylhydrosiloxane) (PMHS) and allyl-poly(ethylene glycol) (APEG) to form core-shell hybrid particles V–SiO2/PMHS/APEG, which showed tunable wettability as well as uniform monodispersity in ethanol and toluene. Particularly, V–SiO2/PMHS/APEG samples with moderate wettability could be served as emulsion stabilizer for silicone oil–water system. The modified particles were characterized by static contact angle (CA), Fourier transform infrared (FT-IR) spectroscopy, FT–Raman spectroscopy, 29Si CP MAS NMR, thermal analysis (TGA), transmission electron microscopy (TEM) and particle size distribution. FT-IR, FT–Raman and 29Si CP MAS NMR demonstrated that PMHS together with APEG was chemically anchored to the surface of nano-SiO2. Deduced from static contact angle, strong hydrophobicity (CA=157.76°) could be achieved for V–SiO2/PMHS particles (m(PMHS):m(V–SiO2)=1:1), while V–SiO2/PMHS/APEG samples exhibited moderate wettability (CA=89.20°) when the mass ratio of V–SiO2, PMHS and APEG was conducted at 1:1:6.0. Thermal analysis (TGA) showed that the grafting yield of PMHS and APEG was 5.76×10−5 and 6.13×10−4mol/g, respectively. V–SiO2/PMHS/APEG samples displayed superior monodispersity in both ethanol and toluene, and the mean diameter was 245.5nm, revealed from particle size distribution. Furthermore, digital photos, optical micrographs and emulsion drop size distribution demonstrated that silicone oil/water emulsions were successfully stabled by the core-shell hybrid particles V–SiO2/PMHS/APEG.