Directed ortho C-H borylation catalyzed using CpRh(iii)-NHC complexes

Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild cond...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 59; pp. 8202 - 8205
Main Authors Thongpaen, Jompol, Schmid, Thibault E., Toupet, Loic, Dorcet, Vincent, Mauduit, Marc, Basle, Olivier
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 19.07.2018
Royal Society of Chemistry
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Summary:Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03144d