Directed ortho C-H borylation catalyzed using CpRh(iii)-NHC complexes

Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild cond...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 59; pp. 8202 - 8205
Main Authors Thongpaen, Jompol, Schmid, Thibault E., Toupet, Loic, Dorcet, Vincent, Mauduit, Marc, Basle, Olivier
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 19.07.2018
Royal Society of Chemistry
Subjects
Aromatic compounds
Chemical Sciences
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Physics
Rhodium
Science & Technology
HETEROCYCLIC CARBENE LIGANDS
ONE-POT SYNTHESIS
IRIDIUM CATALYST
ARENES
C(SP)-H BORYLATION
BOND FORMATION
TRANSFER HYDROGENATION
REGIOSPECIFIC FUNCTIONALIZATION
MULTICOMPONENT SYNTHESIS
RHODIUM COMPLEXES
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Summary:Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03144d