Benzoylbiliverdins from chemical oxidation of dodeca-substituted porphyrins

Oxidation of dodeca-substituted porphyrin 1 in the presence of NaNO2/TFA and air afforded benzoylbiliverdin 3 in 77% yield; under similar conditions the Ni(II)-porphyrin 2 was mainly nitrated at a cyclohexenyl ring; key X-ray structures are presented.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 18; pp. 2298 - 2299
Main Authors Ongayi, O, Fronczek, FR, Vicente, MGH
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.09.2003
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
TETRAPHENYLPORPHYRIN METAL-COMPLEXES
PHOTO-OXYGENATION
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Summary:Oxidation of dodeca-substituted porphyrin 1 in the presence of NaNO2/TFA and air afforded benzoylbiliverdin 3 in 77% yield; under similar conditions the Ni(II)-porphyrin 2 was mainly nitrated at a cyclohexenyl ring; key X-ray structures are presented.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b306586c