CYCLIC VOLTAMMETRY OF 1-(n-HEXYL)-3-METHYL-5-PYRAZOLONE-BASED ENAMINES AND THEIR CHLOROMANGANESE(III) AND NITRIDOMANGANESE(V) COMPLEXES

In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and n...

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Bibliographic Details
Published inJournal of the Chilean Chemical Society Vol. 50; no. 3; pp. 575 - 580
Main Authors PEREZ, F. R., BASÁEZ, L., BELMAR, J., VANYSEK, P.
Format Journal Article
LanguageEnglish
Published Sociedad Chilena de Química 01.09.2005
Subjects
CHEMISTRY, MULTIDISCIPLINARY
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Summary:In this publication we are reporting for the first time on examples of the redox behavior of enamines and complexes derived from 1-alkylpyrazolones. Cyclic voltammetry experiment was performed on three enamines derived from 4-acyl-1-(n-hexyl)-3-methylpyrazol-5-ol and their chloromanganese(III) and nitridomanganese(V) complexes. The ligands have an irreversible oxidation potential of 1.1 V. Chloromanganese(III) complexes are quasi-reversible with an E1/2 of 0.1 V. Nitridomanganese(V) complexes are also quasi-reversible, with E1/2 potentials of 0.95 V. However, for nitridomanganese(V) complexes reversibility increases as the scan speed raises from 100 to 3000 mV·s-1
ISSN:0717-9707
0717-9707
DOI:10.4067/S0717-97072005000300009