Synthesis of sustainable chemicals from waste tea powder and Polystyrene via Microwave-Assisted in-situ catalytic Co-Pyrolysis: Analysis of pyrolysis using experimental and modeling approaches

• Published in: Bioresource technology Vol. 362; p. 127813
• Main Authors: Suriapparao, Dadi V., Sridevi, Veluru, Ramesh, Potnuri, Sankar Rao, Chinta, Tukarambai, M., Kamireddi, Dinesh, Gautam, Ribhu, Dharaskar, Swapnil A., Pritam, Kocherlakota
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2022
• Subjects: Catalyst; Microwave; Polystyrene; Synergistic effect; Waste tea powder; Microwave; Waste tea powder; Synergistic effect; Polystyrene; Catalyst
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2022.127813

[Display omitted] •In-situ catalytic co-pyrolysis was performed for tea waste and polystyrene.•Co-pyrolysis synergy was analyzed to understand its positive effect.•Oil was analyzed for its composition and a reaction mechanism was developed.•Pyrolysis index was evaluated for pyrolysis and co-pyrolysis conditions.•Machine learning analysis was performed to understand the pyrolysis process. In the current study, catalytic co-pyrolysis was performed on waste tea powder (WTP) and polystyrene (PS) wastes to convert them into value-added products using KOH catalyst. The feed mixture influenced the heating rates (17–75 °C/min) and product formation. PS promoted the formation of oil and WTP enhanced the char formation. The maximum oil yield (80 wt%) was obtained at 15 g:5 g, and the maximum char yield (44 wt%) was achieved at 5 g:25 g (PS:WTP). The pyrolysis index (PI) increased with the increase in feedstock quantity. High PI was noticed at 25 g:5 g, and low PI was at 5 g:5 g (PS:WTP). Low energy consumption and low pyrolysis time enhanced the PI value. Significant interactions were noticed during co-pyrolysis. The obtained bio-oil was analyzed using GC–MS and a plausible reaction mechanism is presented. Catalyst and co-pyrolysis synergy promoted the formation of aliphatic and aromatic hydrocarbons by reducing the oxygenated products.