NIR mechanochromic behaviours of a tetracyanoethylene-bridged hexa-peri-hexabenzocoronene dimer and trimer through dissociation of C–C bonds

Oxidation of dicyanomethyl-substituted hexa- peri -hexabenzocoronenes (HBCs) furnished a tetracyanoethylene-bridged HBC dimer and trimer. The solid state structures of the oligomers were elucidated using single crystal X-ray diffraction analysis. In the solution state, these HBC oligomers exhibited...

Full description

Saved in:
Bibliographic Details
Published inJournal of materials chemistry. C, Materials for optical and electronic devices Vol. 5; no. 22; pp. 5310 - 5315
Main Authors Oda, Kazuma, Hiroto, Satoru, Shinokubo, Hiroshi
Format Journal Article
LanguageEnglish
Published 2017
Subjects
Behavior
Carbon-carbon composites
Dimers
Grinding
Oligomers
Radicals
Solvents
Trimers
Online AccessGet full text

Cover

More Information
Summary:Oxidation of dicyanomethyl-substituted hexa- peri -hexabenzocoronenes (HBCs) furnished a tetracyanoethylene-bridged HBC dimer and trimer. The solid state structures of the oligomers were elucidated using single crystal X-ray diffraction analysis. In the solution state, these HBC oligomers exhibited conformational isomerism, depending on solvents and temperatures. Moreover, solid samples of the HBC dimer and trimer exhibited mechanochromism, showing near IR absorption upon grinding through generation of radical species. The formed radical was stable for 4 months, indicating the persistent nature of the radical species. These NIR mechanochromic behaviours of the HBC oligomers were originated from the reversible C–C bond dissociation and formation of a tetracyanoethylene linkage between the HBC units.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2050-7526
2050-7534
DOI:10.1039/C7TC01270E