Nanocellulose Films from Amazon Forest Wood Wastes: Structural and Thermal Properties

The aim of this work was to determine the best fibrillation intensity that should be used to produce high crystalline and thermal stable microfibrillated cellulose (MFC) and nanocellulose films from C. goeldiana veneer wastes. The number of passages (cycles) of cellulose suspension tested in grinder...

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Published inKey Engineering Materials Vol. 668; pp. 110 - 117
Main Authors Bufalino, Lina, Protásio, Thiago de Paula, Sena Neto, Alfredo Rodrigues, Costa, Tattiane Gomes, Guimarães Junior, Mário, Mendes, Lourival Marin, Tonoli, G.H.D., Marconcini, José Manoel
Format Journal Article
LanguageEnglish
Published Zurich Trans Tech Publications Ltd 01.10.2015
Subjects
Biomaterials
Cellulose
Crystal structure
Engineering
Lignin
Nanocomposites
Nanostructure
Surgical implants
Sustainable development
Thermal properties
Wastes
Wood
Initial Degradation Temperature
Crystalline Index
Cellulose
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Abstract The aim of this work was to determine the best fibrillation intensity that should be used to produce high crystalline and thermal stable microfibrillated cellulose (MFC) and nanocellulose films from C. goeldiana veneer wastes. The number of passages (cycles) of cellulose suspension tested in grinder were 10, 20, 30 and 40. Important properties to be analyzed included changes in morphology from the raw wood to the nanocellulose films, increases/decreases in cellulose crystalline index for inference on biomaterial strength, and thermal behavior changes to support conclusions on biomaterials processing and application possibilities. After chemical treatments for cellulose isolation, mechanical shearing was applied to produce cellulose nanostructures; hence nanocellulose films could be successfully produced from C. goeldiana wood wastes. Influence of more refining cycles on thermal properties, indicated higher stability for 40-cycles nanocellulose films. In general, grinder refining process decreased crystalline index of cellulose.
AbstractList The aim of this work was to determine the best fibrillation intensity that should be used to produce high crystalline and thermal stable microfibrillated cellulose (MFC) and nanocellulose films from C. goeldiana veneer wastes. The number of passages (cycles) of cellulose suspension tested in grinder were 10, 20, 30 and 40. Important properties to be analyzed included changes in morphology from the raw wood to the nanocellulose films, increases/decreases in cellulose crystalline index for inference on biomaterial strength, and thermal behavior changes to support conclusions on biomaterials processing and application possibilities. After chemical treatments for cellulose isolation, mechanical shearing was applied to produce cellulose nanostructures; hence nanocellulose films could be successfully produced from C. goeldiana wood wastes. Influence of more refining cycles on thermal properties, indicated higher stability for 40-cycles nanocellulose films. In general, grinder refining process decreased crystalline index of cellulose.
The aim of this work was to determine the best fibrillation intensity that should be used to produce high crystalline and thermal stable microfibrillated cellulose (MFC) and nanocellulose films from C. goeldiana veneer wastes. The number of passages (cycles) of cellulose suspension tested in grinder were 10, 20, 30 and 40. Important properties to be analyzed included changes in morphology from the raw wood to the nanocellulose films, increases/decreases in cellulose crystalline index for inference on biomaterial strength, and thermal behavior changes to support conclusions on biomaterials processing and application possibilities. After chemical treatments for cellulose isolation, mechanical shearing was applied to produce cellulose nanostructures; hence nanocellulose films could be successfully produced from C. goeldiana wood wastes. Influence of more refining cycles on thermal properties, indicated higher stability for 40-cycles nanocellulose films. In general, grinder refining process decreased crystalline index of cellulose.
Author Protásio, Thiago de Paula
Mendes, Lourival Marin
Tonoli, G.H.D.
Sena Neto, Alfredo Rodrigues
Marconcini, José Manoel
Costa, Tattiane Gomes
Guimarães Junior, Mário
Bufalino, Lina
Author_xml – givenname: Lina
  surname: Bufalino
  fullname: Bufalino, Lina
  email: linabufalino@yahoo.com.br
  organization: State University of Amapa : UEAP, Forestry Science Committee
– givenname: Thiago de Paula
  surname: Protásio
  fullname: Protásio, Thiago de Paula
  email: depaulaprotasio@gmail.com
  organization: Federal University of Lavras : UFLA, Forestry Science Department
– givenname: Alfredo Rodrigues
  surname: Sena Neto
  fullname: Sena Neto, Alfredo Rodrigues
  email: alfredosena@yahoo.com.br
  organization: Instrumentation Unit of Brazilian Agriculture Research Corporation – EMBRAPA
– givenname: Tattiane Gomes
  surname: Costa
  fullname: Costa, Tattiane Gomes
  email: tatti_gcosta@yahoo.com.br
  organization: Federal University of Lavras : UFLA, Forestry Science Department
– givenname: Mário
  surname: Guimarães Junior
  fullname: Guimarães Junior, Mário
  email: mgjunior@araxa.cefetmg.br
  organization: Federal Center for Technological Education of Minas Gerais
– givenname: Lourival Marin
  surname: Mendes
  fullname: Mendes, Lourival Marin
  email: lourival@dcf.ufla.br
  organization: Federal University of Lavras : UFLA, Forestry Science Department
– givenname: G.H.D.
  surname: Tonoli
  fullname: Tonoli, G.H.D.
  email: gustavotonoli@yahoo.com.br
  organization: Federal University of Lavras : UFLA, Forestry Science Department
– givenname: José Manoel
  surname: Marconcini
  fullname: Marconcini, José Manoel
  email: jose.marconcini@embrapa.br
  organization: Instrumentation Unit of Brazilian Agriculture Research Corporation – EMBRAPA
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CitedBy_id crossref_primary_10_1016_j_carbpol_2018_11_081
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crossref_primary_10_1007_s12649_018_0295_9
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Crystalline Index
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SubjectTerms Biomaterials
Cellulose
Crystal structure
Engineering
Lignin
Nanocomposites
Nanostructure
Surgical implants
Sustainable development
Thermal properties
Wastes
Wood
Title Nanocellulose Films from Amazon Forest Wood Wastes: Structural and Thermal Properties
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