Combination of aggregation-induced emission and clusterization-triggered emission in mesoporous silica nanoparticles for the construction of an efficient artificial light-harvesting system

• Published in: Journal of materials chemistry. C, Materials for optical and electronic devices Vol. 8; no. 41; pp. 14587 - 14594
• Main Authors: Yan, Saisai, Gao, Zhinong, Yan, Hongyan, Niu, Fei, Zhang, Zhengqin
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 07.11.2020
• Subjects: Agglomeration; Aqueous environments; Emission analysis; Ethanol; Fluorescence; Light emission; Nanoparticles; Rhodamine; Self-assembly; Silicon dioxide; White light
• ISSN: 2050-7526; 2050-7534
• DOI: 10.1039/d0tc03619f

New strategies that can simultaneously overcome the aggregation-caused quenching and enhance the energy-transfer efficiency are still in urgent need. In this study, a superior artificial light-harvesting system (ALHS) with synergetic aggregation-induced emission (AIE) and clusterization-triggered emission (CTE) effects was successfully constructed in an aqueous environment based on the self-assembly of fluorescent mesoporous silica nanoparticles (MSNs) and Rhodamine-B (RB). The AIE effect was provided by the encapsulated fluorescent gemini surfactant C TPE -C 6 -C TPE , while the CTE effect was provided by the ethanol-induced uncommon clusteroluminogens. By properly tuning the concentration of C TPE -C 6 -C TPE , shape-controlled fluorescent MSNs can be facilely prepared, producing spherical MSNs (Ac-100-M) with fascinating fluorescence properties, pH-sensitivity and reversible temperature-sensitive properties. More importantly, multicolor emission can be realized by simply adjusting the concentration of RB, achieving the bright white light emission with a CIE coordinate of (0.33, 0.34) and a fluorescence quantum yield as high as 63.25%. The developed fluorescent MSNs enrich the family of ALHS and provide important insights into the construction of highly efficient multicolored materials for various applications. A highly efficient ALHS was constructed based on the non-covalent assembly of fluorescent MSNs and RB in an aqueous environment.