A hybrid niobium-based oxide with bio-based porous carbon as an efficient electrocatalyst in photovoltaics: a general strategy for understanding the catalytic mechanism

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 7; no. 24; pp. 14864 - 14875
• Main Authors: Wang, Chen, Yun, Sining, Fan, Qingyang, Wang, Ziqi, Zhang, Yangliang, Han, Feng, Si, Yiming, Hagfeldt, Anders
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 2019
• Subjects: Adsorption; Carbon; Catalysis; Catalysts; Catalytic activity; Density functional theory; Electrochemistry; Electrodes; Electron transport; Energy conversion efficiency; First principles; Metals; Niobium; Organic chemistry; Photovoltaic cells; Photovoltaics; Solar cells; Stability analysis; Strategy; Surface chemistry; Synergistic effect
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c9ta03540k

Developing a high-performance catalyst and establishing a catalytic mechanism for understanding the catalytic activity are crucial to new generation photovoltaic technology. In this work, we present a feasible and general route to synthesize a bio-based porous carbon (BPC) supported ZnNb 2 O 6 hybrid catalyst with a unique network structure, providing an effective means for electron transport between the electrode and the external circuit. Benefitting from the synergistic effect of ZnNb 2 O 6 and BPC, a photovoltaic device assembled with the nanohybrid yields a power conversion efficiency of 8.83%, which is superior to that of pristine ZnNb 2 O 6 -based and conventional Pt-based cells (7.15% and 7.14%). Systematic electrochemical evaluations of the hybrid catalysts exhibit promising stability for practical application in photovoltaics. Contraposing the two vital functions of the counter electrode catalyst, collecting electrons and catalyzing I 3 − reduction, we propose a general strategy to understand the potential catalytic mechanism from the band structure and surface adsorption by using first-principles density functional theory (DFT) calculations. The theoretical investigations clearly indicate that the splendid catalytic performance originates from the zero band-gap of surface metal atoms and the surface chemical adsorption interaction between I 3 − and exposed metal atoms. The proposed general strategy in this work for synthesizing a hybrid material with a unique network structure and understanding the catalytic mechanism of the electrocatalyst can guide the design of expected catalytic nanohybrids applied in various energy fields. A general strategy of understanding the catalytic mechanism for a high-performance bio-based porous carbon supported ZnNb 2 O 6 hybrid catalyst is illustrated.