Stereoselective Synthesis of (E)-Vinylsulfides via The Reaction of Vinylzirconium Compounds with Disulfides

Hydrozirconation of alk-1-ynes gives vinyl zirconium complexes, which react with disulfides to afford (E)-vinylic sulfides in high yield.

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Bibliographic Details
Published inSynthetic communications Vol. 29; no. 14; pp. 2399 - 2404
Main Authors Huang, Xian, Xu, Xin-Hua, Zheng, Wei-Xin
Format Journal Article
LanguageEnglish
Published NEW YORK Taylor & Francis Group 01.07.1999
Marcel Dekker Inc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ALKENES
SULFIDES
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Summary:Hydrozirconation of alk-1-ynes gives vinyl zirconium complexes, which react with disulfides to afford (E)-vinylic sulfides in high yield.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919908086245