Stereoselective Synthesis of (E)-(2-Alkyl)- (1-Silylvinyl) Selenides via Hydrozirconation of Alkyl Silyl Acetylenes

• Published in: Synthetic communications Vol. 28; no. 22; pp. 4165 - 4170
• Main Authors: Xu, Xin-Hua, Zheng, Wei-Xin, Huang, Xian
• Format: Journal Article
• Language: English
• Published: NEW YORK Taylor & Francis Group 01.11.1998; Marcel Dekker Inc
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; REACTIVITY

Hydrozirconation of alkyl silyl acetylenes gives organozirconium complexes which reacted with arylselenenyl bromides to afford (E)-(1-silylvinyl)selenides in high yields.