Stereoselective Synthesis of (E)-(2-Alkyl)- (1-Silylvinyl) Selenides via Hydrozirconation of Alkyl Silyl Acetylenes

Hydrozirconation of alkyl silyl acetylenes gives organozirconium complexes which reacted with arylselenenyl bromides to afford (E)-(1-silylvinyl)selenides in high yields.

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Bibliographic Details
Published inSynthetic communications Vol. 28; no. 22; pp. 4165 - 4170
Main Authors Xu, Xin-Hua, Zheng, Wei-Xin, Huang, Xian
Format Journal Article
LanguageEnglish
Published NEW YORK Taylor & Francis Group 01.11.1998
Marcel Dekker Inc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
REACTIVITY
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Summary:Hydrozirconation of alkyl silyl acetylenes gives organozirconium complexes which reacted with arylselenenyl bromides to afford (E)-(1-silylvinyl)selenides in high yields.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919809458696