Stereoselective Total Synthesis of Stagonolide C and Formal Total Synthesis of Modiolide A

The influence of protecting groups at C4 and C7 on a ring-closing metathesis reaction was investigated. Matched induction led to the total synthesis of stagonolide C and the formal total synthesis of modiolide A.

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Bibliographic Details
Published inSynlett no. 13; pp. 2129 - 2132
Main Authors Mohapatra, Debendra K., Dash, Uttam, Naidu, P. Ramesh, Yadav, J. S.
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 13.08.2009
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
modiolide A
ring-closing
DECANOLIDES
metathesis
RING-CLOSING METATHESIS
LACTONES
Sharpless asymmetric epoxidation
stagonolide C
1ST TOTAL-SYNTHESIS
STAGONOSPORA-CIRSII
decanolide
POTENTIAL MYCOHERBICIDE
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Summary:The influence of protecting groups at C4 and C7 on a ring-closing metathesis reaction was investigated. Matched induction led to the total synthesis of stagonolide C and the formal total synthesis of modiolide A.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0029-1217556