Construction of T-Nb2O5 nanoparticles on/in N-doped carbon hollow tubes for Li-ion hybrid supercapacitors

• Published in: Electrochimica acta Vol. 330; p. 135204
• Main Authors: Lian, Yue, Wang, Dawei, Hou, Shuangyue, Ban, Chaolei, Zhao, Jing, Zhang, Huaihao
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 10.01.2020; Elsevier BV
• Subjects: Activated carbon; Anodes; Carbon; Cathodes; Electric vehicles; Electrochemical analysis; Electrode materials; Flux density; Hybrid electric vehicles; Li-ion hybrid capacitors; Lithium; Lithium batteries; Nanoparticles; Nanotubes; Niobium oxides; Niobium pentoxide; Nitrogen doping; Nonaqueous electrolytes; Reaction kinetics; Supercapacitors; Tubes; Ultrafines; Li-ion hybrid capacitors; Nitrogen doping; Niobium pentoxide; Nanotubes
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2019.135204

In recent years, hybrid supercapacitors (HSCs) with good characteristics of both lithium batteries (LIBs) and supercapacitors (SCs) have become a hot research topic to meet the growing market demand for electric and hybrid electric vehicles. The key for high-performance HSCs is the reaction kinetics imbalance between the slow faradaic intercalation anode and fast non-faradaic physical adsorption/desorption cathode. Herein, we simultaneously grow ultrafine Nb2O5 nanoparticles on the inner walls and outer surface of hollow heteroatomic (N) carbon tube, giving a unique hierarchical hybrid nanostructure materials named T-Nb2O5@NC. The LIB test show its excellent high-rate capability and long-term cyclic stability. At current density of 0.25C (1.0–3.0 V, vs Li/Li+), the reversible specific capacity of this material is up to 194 mAh g−1. Importantly, the HSC device, assembled by T-Nb2O5@NC as anode and commercial activated carbon as cathode with an organic electrolyte, exhibits good electrochemical performance, including high energy density (49.7 Wh kg−1) and power density (8750 W kg−1), obviously superior to traditional HSC electrode materials. The results prove that T-Nb2O5@NC can be used as a promising HSC anode material. A hierarchical hybrid nanocomposite (T-Nb2O5@NC), T-Nb2O5 nanoparticles growing on/in both sides of N-doped carbon hollow tubes with stabilized structures upon cycling, is a promising anode material for LIB and HSC. [Display omitted] •Nb2O5 growing on both sides of N-doped carbon hollow tubes (inside and outside surface) relieve volume expansion and improve the rate performances.•The T-Nb2O5@NC//AC HSC delivers high energy density of 49.7 Wh kg-1 at a power density of 8750 W kg-1.•N-doped carbon hollow tubes provides better electrochemical properties.