A Practical Synthesis of Azobenzenes through Oxidative Dimerization of Aromatic Amines Using tert-Butyl Hypoiodite

A straightforward, convenient, and efficient synthetic method of azobenzenes through oxidative dimerization of aromatic amines using a unique and cost-effective iodinating reagent is described. This new method allows for easy access to both of symmetrical and unsymmetrical azobenzenes under extremel...

Full description

Saved in:
Bibliographic Details
Published inSynthesis (Stuttgart) Vol. 45; no. 8; pp. 1029 - 1033
Main Authors Takeda, Youhei, Okumura, Sota, Minakata, Satoshi
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 07.03.2013
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ATMOSPHERIC CO2 FIXATION
azo compounds
T-BUOI
ANILINES
amines
dimerization
oxidation
OLEFINS
iodine
AZO-COMPOUNDS
TBUOI
Online AccessGet more information

Cover

More Information
Summary:A straightforward, convenient, and efficient synthetic method of azobenzenes through oxidative dimerization of aromatic amines using a unique and cost-effective iodinating reagent is described. This new method allows for easy access to both of symmetrical and unsymmetrical azobenzenes under extremely mild conditions.
Bibliography:KAKEN
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0032-1318388