Reduction roasting of hematite to magnetite using carbohydrates

• Published in: International journal of mineral processing Vol. 164; pp. 21 - 25
• Main Authors: Ponomar, V.P., Dudchenko, N.O., Brik, A.B.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 10.07.2017
• Subjects: Hematite; Iron ore; Magnetite; Phase transformation; Thermomagnetic analysis; Hematite; Phase transformation; Magnetite; Thermomagnetic analysis; Iron ore
• ISSN: 0301-7516; 1879-3525
• DOI: 10.1016/j.minpro.2017.05.005

Thermomagnetic analysis was conducted on phase transformations performed for synthetic and natural hematite by reduction involving various carbohydrates (starch, glucose, fructose, sucrose, and ascorbic acid). Thermomagnetic measurements were carried out using a laboratory facility that allows the automatic registration of a sample's magnetization as the temperature changes (the rate of sample heating/cooling was 65°/min). The results were then analyzed. The reduction reaction of synthetic hematite for all carbohydrates starts at a temperature of ~350°C, while the reduction of natural hematite for all carbohydrates starts at a temperature of ~365°C. The magnetite formed by the reaction has a Curie temperature of 565°C. Both magnetite and hematite are present in all transformed samples. Saturation magnetization increases to ~50Am2/kg for the samples obtained from synthetic hematite and ~25Am2/kg for the sample obtained from natural hematite. The difference in the value of saturation magnetization is attributed to a lower magnetite content for the sample obtained from natural hematite. Synthetic hematite transforms more effective, suggesting the synthetic sample is characterized by a larger surface area compared to natural hematite. •Hematite turns into magnetite at 650°C in the presence of carbohydrates.•Slight difference of diverse carbohydrates influence on hematite reduction•New ways of beneficiation of oxidized iron ores