Rheological characterization of metal particle suspension and its relationship with spray-dried granule properties

• Published in: Powder technology Vol. 271; pp. 93 - 99
• Main Authors: Komoda, Yoshiyuki, Takafuji, Daisuke, Suzuki, Hiroshi, Usui, Hiromoto
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.02.2015
• Subjects: Aggregation; Cemented carbide; Spray drying; Surfactant; Suspension rheology; Aggregation; Spray drying; Cemented carbide; Suspension rheology; Surfactant
• ISSN: 0032-5910; 1873-328X
• DOI: 10.1016/j.powtec.2014.10.033

Cemented carbide is usually produced by sintering particles of metal carbides with binders. The non-aqueous suspension of both materials is spray-dried to produce granules having uniform material distribution, resulting in the excellent toughness of final products after sintering. Although the status of particle aggregation in a suspension should have a strong relationship with granule properties, the effect of surfactant on aggregative nature of particles has not been systematically investigated. In the present study, a new instrument was developed to measure apparent viscosity of metal particle suspension without sedimentation in order to investigate particle aggregation from the rheological point of view. Additionally, the particle interaction has been quantitatively evaluated based on Usui's thixotropy model. It is found that the particle interaction was gradually reduced as increasing surfactant concentration, whereas granule properties changed only at higher concentrations. We also found the suspension stability and product functionality are balanced at the critical concentration. The interaction between metal particles in a suspension has been characterized by the inter-particle bonding energy estimated from the viscosity measured by a new viscometer. The morphological properties of spray-dried granules from the suspensions were drastically changed when the bonding energy was less than a critical level. [Display omitted] •Evaluated the interaction of particles for cemented carbide before spray drying•Developed viscometer for volatile solvent based heavy metal particle suspension•Particle interaction is quantitatively estimated from suspension viscosity.•Clarified the relationship between surfactant content and particle interaction•Showed critical level of particle interaction for optimum spray-dried granules