Gold nanoparticles supported on MgOx-Al2O3 composite oxide: An efficient catalyst for selective hydrogenation of acetylene

• Published in: Applied surface science Vol. 487; pp. 625 - 633
• Main Authors: Sun, Xun, Li, Feifei, Shi, Junjie, Zheng, Yuhua, Su, Huijuan, Sun, Libo, Peng, Shuang, Qi, Caixia
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.09.2019
• Subjects: Acetylene hydrogenation; Au nanoparticles; Crystal defect; Decoking; MgOx-Al2O3 composite oxide; MgOx-Al2O3 composite oxide; Acetylene hydrogenation; Au nanoparticles; Crystal defect; Decoking
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2019.05.152

Supported gold nanoparticles are highly selective catalysts for hydrogenation of acetylene, but low activity and heavy coke effect have been major concern for the Au-based catalysts. Based on a modified impregnation-calcination strategy, a series of MgOx-Al2O3 composite oxides with different crystal structures from mixed phase to pure spinel was prepared. Due to its crystal defect and synergetic effect, Au nanoparticles on MgOx-Al2O3 components treated at 550 °C (abbreviated as Au/3%MgOx-Al2O3-550) with well controlled smaller particle size gave an enhanced activity for the selective acetylene hydrogenation. The conversion rate was nearly twice as high as that of all other samples at 250 °C. The H2-TPR and XPS results indicate the partially positive charged Au species (Auδ+) played a crucial role in facilitating the adsorption of the CC group. Both the temperature programmed oxidation and Raman scattering also indicated that the Au/3%MgOx-Al2O3-550 showed better decoking effect than Au/Al2O3. This report opens up promising possibilities on engineering the crystal phase of support for the highly efficient heterogeneous gold catalysts. [Display omitted] •A gold catalyst was obtained by using magnesium-doped alumina as support for the selective hydrogenation of acetylene.•Au species with partially positive charge plays a role in enhancing the acetylene conversion.•The Au/3%MgOx-Al2O3-550 showed better decoking effect and the nature of coke could reveal the mechanism of deactivation.•This procedure opens possibilities of acquiring efficient gold catalysts by engineering the crystal texture of support.