Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds

A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.

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Bibliographic Details
Published inScience China. Chemistry Vol. 59; no. 2; pp. 199 - 202
Main Authors Liu, Yong, Dong, Xichang, Deng, Guojun, Zhou, Lei
Format Journal Article
LanguageEnglish
Published Beijing Science China Press 01.02.2016
Science Press
Springer Nature B.V
Subjects
Aromatic compounds
Chemistry
Chemistry and Materials Science
Chemistry, Multidisciplinary
Chemistry/Food Science
Communications
Darzens反应
Physical Sciences
Science & Technology
偶氮化合物
光合成
光诱导
氮杂环丙烷
甘氨酸
脱羧反应
芳基
aza-Darzens reaction
visible light
diazo compound
decarboxylation
FUNCTIONALIZATION
CONVERSION
AMINES
ACIDS
IMINES
REACTIVITY
GENERATION
PHOTOREDOX CATALYSIS
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Summary:A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.
Bibliography:visible light, diazo compound, decarboxylation, aza-Darzens reaction
A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.
11-5839/O6
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1674-7291
1869-1870
DOI:10.1007/s11426-015-5513-8