POSS-embedded supramolecular hyperbranched polymers constructed from a 1→7 branching monomer with controllable morphology transitions

The research on the supramolecular hyperbranched polymers（SHPs） that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched...

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Bibliographic Details
Published inScience China. Chemistry Vol. 61; no. 3; pp. 311 - 318
Main Authors Wang, Xing, Yang, Yanyu, Fan, Linfeng, Yang, Fei, Wu, Decheng
Format Journal Article
LanguageEnglish
Published Beijing Science China Press 01.03.2018
Springer Nature B.V
Subjects
Aqueous solutions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chromatography
Controllability
Core-shell structure
Materials science
Micelles
Molecular weight
Monomers
Morphology
Oxidation
Polymerization
Polymers
POSS;超分子;聚合物;形态学;单体;控制;嵌入;分叉
Supramolecular polymers
supramolecular hyperbranched polymer
host-guest interaction
morphology transition
POSS-embedded polymer
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Summary:The research on the supramolecular hyperbranched polymers（SHPs） that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers（POSS-SHPs） with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.
Bibliography:POSS-embedded polymer, supramolecular hyperbranched polymer, host-guest interaction, morphology transition
The research on the supramolecular hyperbranched polymers（SHPs） that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers（POSS-SHPs） with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.
11-5839/O6
ISSN:1674-7291
1869-1870
DOI:10.1007/s11426-017-9168-3