Highly crystalline two-dimensional copolymer with dominant face-on orientation for high performance polymer solar cells

• Published in: European polymer journal Vol. 134; p. 109799
• Main Authors: Wang, Shih-Hao, Raja, Rathinam, Yu, Shih-Wei, Jeng, Ru-Jong, Chen, Jyh-Chien, Rwei, Syang-Peng, Wang, Leeyih
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 05.07.2020; Elsevier BV
• Subjects: Absorption spectra; Benzothiadiazole; Copolymers; Crystal structure; Crystallinity; Crystallization; Energy conversion efficiency; Energy levels; Fluorination; Fluoropolymers; Hole mobility; Interlayers; Molecular orbitals; Optoelectronics; Photovoltaic cells; Polyethyleneimine; Polymer solar cell; Solar cells; Solar energy; Space charge; Thiadiazoles; Two-dimensional copolymer; X-ray scattering; Zinc oxide; Two-dimensional copolymer; Benzothiadiazole; Polymer solar cell
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2020.109799

[Display omitted] •Highly crystalline two-dimensional copolymer with vinyl-terthiophene side chain was synthesized for PSCs.•The substitution of fluorine atoms down shifted the HOMO/LUMO energy level.•Introduction of thiophene π-spacer between 2TF and BT promoted dominant face-on orientation and high hole mobility. We designed and synthesized a novel series of two-dimensional (2D) conjugated polymers (P1-2T, P2-2T2F and P3-4T2F) containing 2,2′-bithiophene (2T) and 3,3′-difluoro-2,2′-bithiophene (2T2F) as donor units, and 4,7-benzo[c][1,2,5]thiadiazole (BT) and 4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (DTBT) as acceptor units appended with conjugated vinyl-terthiophene (VTT) side chain. We comprehensively investigated the effect of fluorination and thiophene (T) π-spacer on the optoelectronic properties and photovoltaic performance of the resulting copolymers. In comparison with non-fluorinated polymer P1-2T, the fluorinated polymer P2-2T2F and P3-4T2F had down shifted highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels with an enhanced absorption band. Moreover, 2D grazing incidence wide-angle X-ray scattering and space charge limited current measurement showed that the presence of thiophene π-spacer in P3-4T2F promoted dominant face-on orientation, high crystallinity and enhanced hole mobility, compared with P2-2T2F. As a result, the inverted polymer solar cell based on the P3-4T2F:PC61BM blend exhibited a high power conversion efficiency (PCE) of 6.66% with a Jsc of 12.99 ± 0.30 mA/cm−2. In contrast, the P1-2T:PC61BM and P2-2T2F:PC61BM devices without π-spacer showed a PCE of 2.22% and 0.95%, respectively. The PCE of the P3-4T2F:PC61BM device was further improved to 6.89% by using a polyethylenimine ethoxylated (PEIE) interlayer between ITO and ZnO. This study reinvigorates the key modulation of a 2D conjugated polymer with improved photovoltaic performance.