Methanol dehydration with pervaporation: Experiments and modelling

• Published in: Separation and purification technology Vol. 205; pp. 121 - 129
• Main Authors: Haaz, Eniko, Toth, Andras Jozsef
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 31.10.2018
• Subjects: Hydrophilic membrane; Mathematical modelling; Parameter estimation; Pervaporation, methanol dehydration; Professional flowsheeting environment; Hydrophilic membrane; Parameter estimation; Pervaporation, methanol dehydration; Mathematical modelling; Professional flowsheeting environment
• ISSN: 1383-5866; 1873-3794
• DOI: 10.1016/j.seppur.2018.04.088

•Polyvinyl-alcohol membrane is able to remove the water from methanol.•Two different pervaporation model are tested on our experimental data.•The improved novel model results in a better fit to the experimental data.•Improved model is able to describe pervaporation in flowsheet environment.•Heat duties of pervaporation dehydration is lower than distillation. The research is motivated by a pharmaceutical industry problem where water should be removed from the aqueous mixture of methanol. To complete this target, pervaporation system is designed using hydrophilic Sulzer PERVAP™ 1510 membranes and examined to obtain information about the separation of methanol–water mixture. The aim of this work is to rigorously model and optimize the dewatering process. Separation factors, total and partial permeation fluxes, permeances and selectivities are experimentally determined. Pervaporation separation index (PSI) data are compared to those of other published membranes in the recent literature and it is found that PERVAP™ 1510 has the highest PSI value. The measured data are evaluated with improved pervaporation model by Valentínyi et al. (2013) and it is found that the model can be applied also for this hydrophilic separation case. The separation system is rigorously modelled with ChemCAD and optimized with the dynamic programming optimization method. Such methanol–water separation has not been published in this professional flowsheet environment yet. The objective function of the process is the effective membrane area. The methanol dehydration is also investigated with distillation in flowsheet environment. It can be determined that pervaporation system is capable for the dehydration of methanol and it can become the alternative of distillation based separation, because it has lower heat duties in the case of same product compositions.