Preparation and Characterization of CA-MA Eutectic/Silicon Dioxide Nanoscale Composite Phase Change Material from Water Glass via Sol-Gel Method

• Published in: Journal of Wuhan University of Technology. Materials science edition Vol. 32; no. 5; pp. 1048 - 1056
• Main Author: 孟多;ZHAO Kang;ZHAO Wei;JIANG Guowei
• Format: Journal Article
• Language: English
• Published: Wuhan Wuhan University of Technology 01.10.2017; Springer Nature B.V
• Subjects: Advanced Materials; Chemical bonds; Chemistry and Materials Science; Coupling agents; Differential scanning calorimetry; Energy conservation; Energy storage; Eutectic temperature; Fourier transforms; Heat conductivity; Heat measurement; Heat storage; Heat transfer; Latent heat; Materials Science; Phase change materials; Scanning electron microscopy; Silica; Silicon dioxide; Sol-gel processes; Stability; Storage capacity; Thermal analysis; Thermal conductivity; Thermal energy; Thermal insulation; Thermal storage; Thermodynamic properties; Transient hot wire method; 傅立叶变换红外光谱; 共晶; 复合相变材料; 水玻璃; 溶胶-凝胶法; 玻璃制备; 纳米二氧化硅; 纳米尺度; water glass; fatty acid eutectic; silicon dioxide; nanoscale composite phase change material; sol-gel
• ISSN: 1000-2413; 1993-0437
• DOI: 10.1007/s11595-017-1709-4

This work mainly involved the preparation of a nano-scale form-stable phase change material（PCM） consisting of capric and myristic acid（CA-MA） binary eutectic acting as thermal absorbing material and nano silicon dioxide（nano-SiO_2） serving as the supporting material. Industrial water glass for preparation of the nano silicon dioxide matrix and CA-MA eutectic mixture were compounded by single-step sol-gel method with the silane coupling agent. The morphology, chemical characterization and form stability property of the composite PCM were investigated by transmission electron microscopy（TEM）, scanning electron microscopy（SEM）, Fourier-transform infrared（FT-IR） spectroscopy and polarizing microscopy（POM）. It was indicated that the average diameter of the composite PCM particle ranged from 30-100 nm. The CA-MA eutectic was immobilized in the network pores constructed by the Si-O bonds so that the composite PCM was allowed no liquid leakage above the melting temperature of the CA-MA eutectic. Differential scanning calorimetry（DSC） and thermogravimetric analysis（TGA） measurement were conducted to investigate the thermal properties and stability of the composite PCM. From the measurement results, the mass fraction of the CA-MA eutectic in the composite PCM was about 40%. The phase change temperature and latent heat of the composite were determined to be 21.15 ℃ and 55.67 J/g, respectively. Meanwhile, thermal conductivity of the composite was measured to be 0.208 W·m~（-1）·K~（-1） by using the transient hot-wire method. The composite PCM was able to maintain the surrounding temperature close to its phase change temperature and behaved well in thermalregulated performance which was verified by the heat storage-release experiment. This kind of form-stable PCM was supposed to complete thermal insulation even temperature regulation by the dual effect of relatively low thermal conductivity and phase change thermal storage-release properties. So it can be formulated that the nanoscale CA-MA/SiO_2 composite PCM with the form-stable property, good thermal storage capacity and relatively low thermal conductivity can be applied for energy conservation as a kind of thermal functional material.