Iron Catalysis and Water: A Synergy for Refunctionalization of Boron

A new catalytic system has been optimized to promote the conversion of boron species into others. FeCl3 associated with imidazole and water favors boron refunctionalization under mild conditions.

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Bibliographic Details
Published inSynlett Vol. 25; no. 4; pp. 551 - 555
Main Authors Wood, John L., Marciasini, Ludovic D., Vaultier, Michel, Pucheault, Mathieu
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 03.03.2014
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
PALLADIUM
ASYMMETRIC 1,4-ADDITIONS
HYDROLYSIS
DEPROTECTION
water
SALTS
boronate
CROSS-COUPLING REACTIONS
homogeneous catalysis
ARYL HALIDES
ESTERS
iron
boron
BORYLATION
ACCESS
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Summary:A new catalytic system has been optimized to promote the conversion of boron species into others. FeCl3 associated with imidazole and water favors boron refunctionalization under mild conditions.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0033-1340500