Effects of low melting point metals (Ga, In, Sn) on hydrolysis properties of aluminum alloys
Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al–In–Sn and Al–Ga–In–Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction (XRD) and sca...
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| Published in | Transactions of Nonferrous Metals Society of China Vol. 26; no. 1; pp. 152 - 159 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
01.01.2016
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| Abstract | Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al–In–Sn and Al–Ga–In–Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy disperse spectroscopy (EDS) were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al–In–Sn ternary alloys are Al and two intermetallic compounds, In3Sn and InSn4. All Al–In–Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al–In–Sn alloy with the mass ratio of In to Sn equaling 1:4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga–In3Sn–InSn4 eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity. |
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| AbstractList | Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al–In–Sn and Al–Ga–In–Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy disperse spectroscopy (EDS) were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al–In–Sn ternary alloys are Al and two intermetallic compounds, In3Sn and InSn4. All Al–In–Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al–In–Sn alloy with the mass ratio of In to Sn equaling 1:4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga–In3Sn–InSn4 eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity. Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy disperse spectroscopy (EDS) were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al-In-Sn ternary alloys are Al and two intermetallic compounds, In sub(3)Sn and InSn sub(4). All Al-In-Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al-In-Sn alloy with the mass ratio of In to Sn equaling 1:4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga-In sub(3)Sn-InSn sub(4) eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity. |
| Author | WANG, Hui-hu LUO, Ping WANG, Jian LU, Jia MA, Xin-guo DONG, Shi-jie WANG, Fan-qiang CHANG, Ying |
| Author_xml | – sequence: 1 givenname: Fan-qiang surname: WANG fullname: WANG, Fan-qiang organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 2 givenname: Hui-hu surname: WANG fullname: WANG, Hui-hu email: wanghuihu@mail.hbut.edu.cn organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 3 givenname: Jian surname: WANG fullname: WANG, Jian organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 4 givenname: Jia surname: LU fullname: LU, Jia organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 5 givenname: Ping surname: LUO fullname: LUO, Ping organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 6 givenname: Ying surname: CHANG fullname: CHANG, Ying organization: School of Materials Science and Engineering, Hubei University of Technology, Wuhan 430068, China – sequence: 7 givenname: Xin-guo surname: MA fullname: MA, Xin-guo organization: School of Science, Hubei University of Technology, Wuhan 430068, China – sequence: 8 givenname: Shi-jie surname: DONG fullname: DONG, Shi-jie organization: School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China |
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| Keywords | low melting point metal mechanical ball milling method aluminum alloy hydrolysis hydrogen generation |
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| Snippet | Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al–In–Sn and Al–Ga–In–Sn alloys through mechanical ball milling method. The... Low melting point metals (Ga, In, Sn) as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The... |
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| SubjectTerms | Alloys aluminum alloy Aluminum base alloys Gallium base alloys hydrogen generation Hydrolysis low melting point metal mechanical ball milling method Melting points Scanning electron microscopy Ternary alloys Tin |
| Title | Effects of low melting point metals (Ga, In, Sn) on hydrolysis properties of aluminum alloys |
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