Quantifying instant water cleaning efficiency using zinc oxide decorated complex 3D printed porous architectures

• Published in: Journal of hazardous materials Vol. 418; p. 126383
• Main Authors: Kumbhakar, Partha, Ambekar, Rushikesh S., Mahapatra, Preeti Lata, Sekhar Tiwary, Chandra
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.09.2021
• Subjects: 3D printing; Colorimetric detection; Dye degradation; Photocatalytic activity; ZnO nanosheets; Photocatalytic activity; Dye degradation; ZnO nanosheets; 3D printing; Colorimetric detection
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2021.126383

Industrialization harms the quality of water; therefore, cleaning and monitoring water sources are essential for sustainable human health and aquatic life. An increase in active surface area and porosity can result in quick and efficient cleaning activity. 3D printing can build porous architecture with controlled porosity and active surface area. Here, catalytically active ZnO nanosheets were grown on the surface of 3D printed architecture (Schwarzites and Weissmuller) with different porosity and surface area. The Weissmuller structure along with ZnO, has shown better catalytic performance due to its higher porosity (~69%) and high active surface area, compared to Schwarzites structure. Synergistic effect of adsorption and photodegradation has resulted in ~95% removal efficiency of mixed dye within 10 min by Weissmuller structure. The dye degradation efficiency was determined using colorimetric measurements with a regular smartphone for real-time quantitative investigation of dye removal efficiency. Most importantly, decorated 3D printed structures exhibit high structural stability without residuals (ZnO nanosheets) in water after performing the recycling experiment. Therefore, the decorated 3D printing structures and colorimetric detection method will offer a user-friendly versatile technique for analysis of removal efficiency of toxic components in different polluted water sources without using high-end sophisticated instruments and complicated procedures. [Display omitted] •3D printed polymer scaffold with different geometry and surface porosity.•In situ growth of ZnO nanoflakes on 3D printed scaffolds.•The synergistic effect between the photodegradation and adsorption in a one system.•Smartphone-based user-friendly facile detection of dye removal efficiency.•RGB calculation for quantitative analysis using colorimetric absorption technique.