Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane

Reaction of the first homoleptic U(iii) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(iii) to U(v) and isolation of a U(v) hydrazido complex. Corresponding U(v) imido, U(v) oxo, and U(iv) azido complexes were also synthesized for structural comparison.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 54; no. 77; pp. 10913 - 10916
Main Authors Settineri, Nicholas S, Shiau, Angela A, Arnold, John
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Royal Society of Chemistry (RSC)
Subjects
Crystallography
Oxidation
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Summary:Reaction of the first homoleptic U(iii) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(iii) to U(v) and isolation of a U(v) hydrazido complex. Corresponding U(v) imido, U(v) oxo, and U(iv) azido complexes were also synthesized for structural comparison.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
AC02-05CH11231
USDOE Office of Science (SC), Basic Energy Sciences (BES)
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc06514d