Highly efficient and selective adsorption of heavy metal ions by hydrazide-modified sodium alginate

• Published in: Carbohydrate polymers Vol. 276; p. 118797
• Main Authors: Shi, Tianzhu, Xie, Zhengfeng, Zhu, Zhu, Shi, Wei, Liu, Yucheng, Liu, Minyao
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.01.2022
• Subjects: Adsorption; Heavy metal ions; Hydrazide–modified; Sodium alginate; Heavy metal ions; Sodium alginate; Adsorption; Hydrazide–modified
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2021.118797

In the present study, a new potential adsorbent for the separation and removal of heavy metal ions was prepared using hydrazide modification. Characterization of structural and chemical properties of the absorbent indicated the dialdehyde sodium alginate (DSA) grafted adipic acid dihydrazide (AAD) plays a crucial role. The adsorption process correlated well with Freundlich isotherm and pseudo-second-order kinetics models. Additionally, the adsorption capacities for Hg2+, Pb2+, Cd2+, and Cu2+ were 7.833, 2.036, 4.766, and 3.937 mmol g−1, respectively. The thermodynamic parameter for the sorption demonstrated the process is endothermic and spontaneous. FT-IR and XPS analysis revealed the combination of chelation interactions and ion exchange between nitrogen, oxygen atoms and heavy metal ions. Moreover, after 10 times adsorption–desorption recycles, the adsorption efficiency of the adsorbent was slightly decreased. In conclusion, the as-prepared adsorbent has great potential in practical water pollution purification. Hydrazide-modified sodium alginate (DSA-AAD@Ca2+) was prepared through dialdehyde sodium alginate (DSA) and adipic acid dihydrazide (AAD) dehydrated and condensed by Schiff base reaction, and then followed by ion exchange with Ca2+. DSA-AAD@Ca2+ exhibited the excellent adsorption performance for heavy metal ions (Hg2+, Pb2+, Cd2+, and Cu2+). The adsorption capacities for Hg2+, Pb2+, Cd2+, and Cu2+ were 7.833, 2.036, 4.766, and 3.937 mmol g−1, respectively. Moreover, after 10 times adsorption–desorption recycles, the adsorption efficiency of the adsorbent was slightly decreased. [Display omitted]