Ionic Interactions in Alkali -Aluminium Tetrafluoride Clusters

• Published in: Zeitschrift für Naturforschung. A, A journal of physical sciences Vol. 54; no. 10; pp. 570 - 574
• Main Authors: Akdeniz, Z., Çiçek, Z., Karaman, A., Pastore, G., Tosi, M. P.
• Format: Journal Article
• Language: English
• Published: Verlag der Zeitschrift für Naturforschung 01.11.1999
• Subjects: Alkali -Aluminium Tetrafluoride; Charged Clusters; Structure of Associated Liquids
• ISSN: 0932-0784; 1865-7109
• DOI: 10.1515/zna-1999-10-1102

Complex anion structures ((AlF , (AlF and (AIF ) coexist in liquid mixtures of alu-minium trifluoride and alkali fluorides in composition-dependent relative concentrations and are known to interact with the alkali counterions. We present a comparative study of the static and vibrational structures of MA1F molecules (with M = any alkali), with the aim of developing and testing a refined model of the ionic interactions for applications to the M-Al fluoride mixtures. We find that, whereas an edge-bridged coordination is strongly favoured for Li in LiAlF , edge-bridging and face-bridging of the alkali ion become energetically equivalent as one moves from Na to the heavier alkalis. This result is sensitive to the inclusion of alkali polarizability and may be interpreted as implying (for M = K, Rb or Cs) almost free relative rotations of the M and (AlF partners at temperatures of relevance to experiment. The consistency of such a viewpoint with electron diffraction data on vapours and with Raman spectra on melts is discussed.