Preparation of Pd-PS, Pd-PSB and Pd-PSC nanoparticles by γ-irradiation and their catalytic efficiency in Sonogashira coupling reaction
The poly(styrene), PS, of 450nm diameter, poly(styrene-co-4-vinylphenylboronic acid), PSB, nanoparticles of 220–400nm diameter, and poly(styrene-co-4-vinylbenzoic acid), PSC, nanoparticles of 240–305nm were prepared by emulsifier-free emulsion polymerization. The surface of PS, PSB, and PSC nanopart...
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Published in | Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 313-314; pp. 224 - 229 |
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Main Authors | , , , , , |
Format | Journal Article Conference Proceeding |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.02.2008
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | The poly(styrene), PS, of 450nm diameter, poly(styrene-co-4-vinylphenylboronic acid), PSB, nanoparticles of 220–400nm diameter, and poly(styrene-co-4-vinylbenzoic acid), PSC, nanoparticles of 240–305nm were prepared by emulsifier-free emulsion polymerization. The surface of PS, PSB, and PSC nanoparticles were loaded with Pd nanoparticles by reduction of Pd ions using γ-irradiation in order to apply catalyst in Sonogashira coupling reaction. The Pd-PS, Pd-PSB and Pd-PSC were characterized by High-Resolution Transmittance Electron Microscopy (HR-TEM), Field-Emission Scanning Electron Microscopy (FE-SEM), and Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES), respectively. The HR-TEM, XRD and ICP-AES data show that the Pd nanoparticles were loaded on the surface of PS, PSB, and PSC nanoparticles, respectively. Catalytic efficiency of the Pd-PS, Pd-PSB and Pd-PSC nanoparticles was tested in Sonogashira coupling reaction. The catalytic efficiency of the Pd-PS, Pd-PSB, and Pd-PSC nanoparticles was increased with increasing Pd nanoparticle contents. |
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ISSN: | 0927-7757 1873-4359 |
DOI: | 10.1016/j.colsurfa.2007.05.041 |