Insight into the role of the zeolitization process in enhancing the adsorption performance of kaolinite/diatomite geopolymer for effective retention of Sr (II) ions; batch and column studies
Diatomite/kaolinite-based geopolymer (GP) was synthesized and incorporated in zeolitization process (Z/GP) to investigate the role of the zeolite phases in inducing its retention capacity of the dissolved Sr (II) ions in water. The retention of Sr (II) ions using Z/GP in comparison with GP was evalu...
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Published in | Journal of environmental management Vol. 294; p. 112984 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
15.09.2021
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Subjects | |
Online Access | Get full text |
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Summary: | Diatomite/kaolinite-based geopolymer (GP) was synthesized and incorporated in zeolitization process (Z/GP) to investigate the role of the zeolite phases in inducing its retention capacity of the dissolved Sr (II) ions in water. The retention of Sr (II) ions using Z/GP in comparison with GP was evaluated based on both batch and fixed-bed column studies. In the batch study, the zeolitized geopolymer (Z/GP) shows enhancement in the Sr (II) retention capacity (193.7 mg/g) as compared to the normal geopolymer (102 mg/g). Moreover, the recyclability studies demonstrate higher stability for Z/GP than GP with a retention percentage higher than 90% for five reusing runs. The kinetic and the equilibrium properties of the occurred Sr (II) retention reactions follow the assumption of the Pseudo-Second order model (R2 > 0.96) and Langmuir model (R2 > 0.97), respectively. The Gaussian energies (15.4 kJ/mol (GP) and 11.47 kJ/mol (Z/GP)) related to retention mechanism of chemical type and within the suggested range for the zeolitic ion exchange processes. The Sr (II) retention reactions by GP and Z/GP are of spontaneous and exothermic properties which qualifies the products to be used at low-temperature conditions (20 °C). The column studies also declared higher performance for the Z/GP fixed bed as compared to the normal GP bed considering the total Sr (II) retention percentage (72.9%), treated volume (8 L), saturation time (1620 min), and a maximum capacity of Z/GP particles in the bed (567.6 mg/g).
•Zeolitized geopolymer product was synthesized for enhanced retention of Sr (II).•The qmax of the geopolymer and the zeolitized product are 102 mg/g and 193.7 mg/g.•The retention reactions of Sr (II) follow Langmuir and Pseudo-Second order models.•The retention process occurred by chemical, exothermic and spontaneous reactions.•The column tests show higher retention by the zeolitized product than geopolymer. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0301-4797 1095-8630 |
DOI: | 10.1016/j.jenvman.2021.112984 |