Photothermal graphene/UiO-66-NH2 fabrics for ultrafast catalytic degradation of chemical warfare agent simulants

• Published in: Journal of hazardous materials Vol. 393; p. 122332
• Main Authors: Song, Linna, Zhao, Tianyu, Yang, Dongzhi, Wang, Xuejiao, Hao, Xinmin, Liu, Yaxin, Zhang, Shiyi, Yu, Zhong-Zhen
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.07.2020
• Subjects: Catalytic degradation; Chemical warfare agents; Graphene fabrics; Metal-organic frameworks; Photothermal conversion; Chemical warfare agents; Catalytic degradation; Metal-organic frameworks; Photothermal conversion; Graphene fabrics
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2020.122332

[Display omitted] •Photothermal graphene/MOF fabrics are synthesized for degrading simulants of CWAs.•The flexible fabric exhibits ultrafast photothermal catalytic degradation of DMNP.•Photothermal conversion of graphene accelerates catalytic reaction kinetics of MOFs. Lightweight and wearable fabrics with rapid self-detoxification functions are highly desired to resist chemical warfare agents (CWAs). Metal organic frameworks (MOFs) with high specific surface area and customizability are singularly attractive because of their ability to effectively capture and catalytically degrade CWAs. Herein, photothermal graphene-based nanocomposite fabrics are designed by wet-spinning and chemical reduction of graphene oxide fibers followed by in situ growth of UiO-66-NH2. The flexible graphene fabrics decorated with UiO-66-NH2 nanoparticles exhibit an ultrafast photothermal catalytic decontamination of dimethyl 4-nitrophenyl phosphate (DMNP), a typical simulant of CWAs. The half-life of the degradation reaction decreases from 3.4 to 1.6 min under simulated solar light irradiation, a significant gain over the values reported in the literature. Furthermore, DMNP can be degraded in 20 min by the graphene/UiO-66-NH2 fabric, and even after 5 cycles the degradation efficiency still retains more than 92 %. More importantly, the photothermal conversion of graphene and its instantaneous heat transfer to the UiO-66-NH2 catalyst effectively accelerate the catalytic reaction kinetics, achieving the fast detoxification of DMNP. The combination of catalytic degradation of MOFs with photothermal conversion effect of graphene makes the lightweight and flexible fabrics promising for protection against CWAs and other pollutants.