Separation of zinc, cadmium and nickel from ZnO–CdO–NiO mixture through baking with ammonium chloride and leaching

• Published in: Hydrometallurgy Vol. 119-120; pp. 1 - 7
• Main Authors: Turan, M. Deniz, Safarzadeh, M. Sadegh
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.05.2012; Elsevier
• Subjects: Ammonium chloride; Applied sciences; Cadmium; Cd–Ni purification residues; Exact sciences and technology; Metals. Metallurgy; Nickel; Production of metals; Zinc; Ammonium chloride; Cadmium; Nickel; Cd–Ni purification residues; Zinc; Purification; Separation; Lixiviation; Hydrometallurgy; Cd-Ni purification residues
• ISSN: 0304-386X; 1879-1158
• DOI: 10.1016/j.hydromet.2012.03.006

As part of a continuing effort, the separation of cadmium, nickel and zinc from ZnO–CdO–NiO mixture has been addressed to simulate the conditions encountered in Cd–Ni zinc plant purification residues. For this purpose, mixtures of ZnO, CdO, and NiO were baked at fairly low temperatures (200–400°C) in the presence of ammonium chloride. As a result of baking, almost complete conversion of metals to their corresponding chlorides was achieved. While baking process provided no selectivity of metals, the subsequent water leaching process was successfully employed for the selective separation of metals based on leaching at different pH values. A factorial design of experiments was used to examine the main effects of the experimental parameters on the response. The proposed model fitted well to the experimental data according to R2 and R2adj correlation coefficients of response values. This procedure enabled the selective separation and concentration of zinc from the mixture. Ammonium chloride baking and leaching of a Cd–Ni zinc plant purification residue sample under similar conditions resulted in 88.1% Ni, 96.7% Cd, and less than 1% Zn extractions, showing a good agreement with the experimental results obtained from pure oxide mixtures. The findings of this research appear to be useful for the treatment of Cd–Ni zinc plant purification residues. [Display omitted] ► ZnO, CdO, and NiO formed chlorides through baking with ammonium chloride. ► Water leaching was successfully employed for the selective separation of metals. ► The procedure was used for the treatment of zinc plant purification residues. ► Baking of real ZPR indicated similar behavior as the mixture of pure oxides. ► The simulations with STABCAL software appeared to be very reliable.