Steroids. III. New Synthesis of Ring-D Seco Steroids
16β-Azido-5α-androstan-17-one derivatives were cleaved with bromine in acetic acid at room temperature, to furnish 16-cyano and 16-carbamoyl-16,17-seco-5α-androstan-17-oic acids. 17-Aza-D-homo-5α-androstan-16,17a-dione derivatives were also synthesized.
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| Published in | Bulletin of the Chemical Society of Japan Vol. 56; no. 1; pp. 355 - 356 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
The Chemical Society of Japan
01.01.1983
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| Online Access | Get full text |
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| Summary: | 16β-Azido-5α-androstan-17-one derivatives were cleaved with bromine in acetic acid at room temperature, to furnish 16-cyano and 16-carbamoyl-16,17-seco-5α-androstan-17-oic acids. 17-Aza-D-homo-5α-androstan-16,17a-dione derivatives were also synthesized. |
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| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.56.355 |