Absorption Intensity of Stretching Overtone States of Silane and Germane
The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1–5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived...
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Published in | Journal of molecular spectroscopy Vol. 192; no. 2; pp. 249 - 256 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
Elsevier Inc
01.12.1998
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Online Access | Get full text |
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Summary: | The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1–5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived by linear least-squares fitting. The relative intensities of overtones can be satisfactorily reproduced with the bond dipole model containing two adjustable parameters. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0022-2852 1096-083X |
DOI: | 10.1006/jmsp.1998.7673 |