Absorption Intensity of Stretching Overtone States of Silane and Germane

The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1–5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived...

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Bibliographic Details
Published inJournal of molecular spectroscopy Vol. 192; no. 2; pp. 249 - 256
Main Authors Lin, Hai, Wang, Dong, Chen, Xi-Yi, Wang, Xiao-Gang, Zhou, Zhong-Ping, Zhu, Qing-Shi
Format Journal Article
LanguageEnglish
Published United States Elsevier Inc 01.12.1998
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Summary:The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1–5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived by linear least-squares fitting. The relative intensities of overtones can be satisfactorily reproduced with the bond dipole model containing two adjustable parameters.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1998.7673