Heck reaction with heteroaryl halides in the presence of a palladium-tetraphosphine catalyst

cis, cis, cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/ 1 2 [PdCl(C3H5)]2 system catalyses efficiently the Heck reaction of heteroaryl halides with n-butyl acrylate, styrene, vinylpyridine and vinyl ether derivatives. High turnover numbers can be obtained for the reactions with halo pyr...

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Bibliographic Details
Published inTetrahedron letters Vol. 43; no. 32; pp. 5625 - 5628
Main Authors Berthiol, Florian, Feuerstein, Marie, Doucet, Henri, Santelli, Maurice
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 05.08.2002
Elsevier
Subjects
Chemical Sciences
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
PYRIMIDINE-DERIVATIVES
CROSS-COUPLING REACTION
PALLADACYCLES
VINYLATION
ARYL HALIDES
STYRENE
EFFICIENT CATALYSTS
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Summary:cis, cis, cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/ 1 2 [PdCl(C3H5)]2 system catalyses efficiently the Heck reaction of heteroaryl halides with n-butyl acrylate, styrene, vinylpyridine and vinyl ether derivatives. High turnover numbers can be obtained for the reactions with halo pyridines, quinolines, furans or thiophenes. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(02)01109-7